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Abstract Global climate change has impacted ocean biogeochemistry and physical dynamics, causing increases in acidity and temperature, among other phenomena. These changes can lead to deleterious effects on marine ecosystems and communities that rely on these ecosystems for their livelihoods. To better quantify these changes, an array of floats fitted with biogeochemical sensors (BGC‐Argo) is being deployed throughout the ocean. This paper presents an algorithm for deriving a deployment strategy that maximizes the information captured by each float. The process involves using a model solution as a proxy for the true ocean state and carrying out an iterative process to identify optimal float deployment locations for constraining the model variance. As an example, we use the algorithm to optimize the array for observing ocean surface dissolved carbon dioxide concentrations (pCO₂) in a region of strong air–sea gas exchange currently being targeted for BGC‐Argo float deployment. We conclude that 54% of the pCO₂variability in the analysis region could be sampled by an array of 50 Argo floats deployed in specified locations. This implies a relatively coarse average spacing, though we find the optimal spacing is nonuniform, with a denser sampling being required in the eastern equatorial Pacific. We also show that this method could be applied to determine the optimal float deployment along ship tracks, matching the logistics of real float deployment. We envision this software package to be a helpful resource in ocean observational design anywhere in the global oceans. 

Abstract The Southern Ocean (SO) plays a crucial role in the process of sequestering heat and carbon dioxide from the atmosphere and transferring them to the deep ocean. This process is intricately linked to the formation of Antarctic Intermediate Water (AAIW) and Subantarctic Mode Water (SAMW), which are pivotal components of the Meridional Overturning Circulation (MOC) and have a substantial impact on the global climate balance. AAIW and SAMW take shape in specific regions of the Southern Ocean due to the influence of strong winds, buoyancy fluxes, and their effects, such as convection, the development of thick mixed layers, and wind‐driven subduction. These water masses subsequently flow northward, contributing to the ventilation of the intermediate layers within the subtropical gyres. In this study, our focus lies on investigating the regional aspects of AAIW and SAMW transformation in CMIP6 models. We accomplish this by analyzing the relationship between the meridional transport of these water masses and air‐sea fluxes, particularly Ekman pumping, freshwater fluxes, and heat fluxes. Our findings reveal that the highest transformation rates occur in the Indian sector of the Southern Ocean, with notable values also observed in the southeast Pacific and south of Africa. Additionally, we assess the potential changes in these formation regions under future scenarios projected for the end of the 21st century. Although the patterns of formation regions remain consistent, there is a significant decrease in the transformation process. 

Abstract Ocean surface rain layers (RLs) form when relatively colder, fresher, less dense rain water stably stratifies the upper ocean. RLs cool sea surface temperature (SST) by confining surface evaporative cooling to a thin near‐surface layer, and generate sharp SST gradients between the cool RL and the surrounding ocean. In this study, ocean‐atmosphere coupled simulations of the November 2011 Madden‐Julian Oscillation (MJO) event are conducted with and without RLs to evaluate two pathways for RLs to influence the atmosphere. The first, termed the “SST gradient effect,” arises from the hydrostatic adjustment of the boundary layer to RL‐enhanced SST gradients. The second, termed the “SST effect,” arises from RL‐induced SST reductions impeding the development of deep atmospheric convection. RLs are found to sharpen SST gradients throughout the MJO suppressed and suppressed‐to‐enhanced convection transition phases, but their effect on convection is only detected during the MJO suppressed phase when RL‐induced SST gradients enhance low‐level convergence/divergence and broaden the atmospheric vertical velocity probability distribution below 5 km. The SST effect is more evident than the SST gradient effect during the MJO transition phase, as RLs reduce domain average SST by 0.03 K and narrow vertical velocity distribution, thus delaying onset of deep convection. A delayed SST effect is also identified, wherein frequent RLs during the MJO transition phase isolate accumulated subsurface ocean heat from the atmosphere. The arrival of strong winds at the onset of the MJO active phase erodes RLs and releases subsurface ocean heat to the atmosphere, supporting the development of deep convection. 

Abstract In the tropical Pacific, weak ventilation and intense microbial respiration at depth give rise to a low dissolved oxygen (O₂) environment that is thought to be ventilated primarily by the equatorial current system (ECS). The role of mesoscale eddies and vertical mixing as potential pathways of O₂supply in this region, however, remains poorly known due to sparse observations and coarse model resolution. Using an eddy resolving simulation of ocean circulation and biogeochemistry, we assess the contribution of these processes to the O₂budget balance and find that vertical mixing of O₂, which is modulated by the surface wind speed and the vertical shear of the eddying currents, contributes substantially to the replenishment of O₂in the upper equatorial Pacific thermocline, complementing the advective supply of O₂by the ECS and meridional circulation at depth. These transport processes vary seasonally in conjunction with the wind: mixing of O₂into the upper thermocline is strongest during boreal summer and fall when the vertical shear and eddy kinetic energy are intensified. The relationship between eddy activity and the downward mixing of O₂arises from the modulation of equatorial turbulence by Tropical Instability Waves via their impacts on the vertical shear. This interaction of processes across scales sustains a local pathway of O₂delivery into the equatorial Pacific interior and highlights the need for adequate observations and models of turbulent mixing and mesoscale processes for understanding and predicting the fate of the tropical Pacific O₂content in a warmer and more stratified ocean.